NPS:  Thoma-Others-2011

Title
Documenting Measurement Sensitivity and Bias of FIeld-Measured Parameters in Water Quality Monitoring Programs
Author
Thoma, D.P., Irwin, R.J., and Penoyer, P.E.
Abstract/Summary Statement
Measurement sensitivity and bias quality control metrics are commonly reported for waterquality parameters measured in the laboratory. Less commonly recognized is that they should also be reported for field-measured parameters. Periodic evaluation helps document data quality and can help serve as early warning if there are problems with methods or techniques that could negatively affect ability to interpret threshold values and trends over time. This study focuses on traditional assessment of bias and introduces a new method for estimating measurement sensitivity of water-quality parameters measured monthly in the field. Alternative measurement sensitivity is a new data quality indicator used to demonstrate how quantifying sensitivity at the measurement level can improve understanding the uncertainty affecting each reported data value. That, in turn, can help interpret the meaning of results from many separate data points measured in the field. In this 30-month study, pH and specific conductance consistently met, and dissolved oxygen did not always meet NPS and USGS quality control standards for bias. Evaluation of dissolved oxygen bias and sensitivity during the study provided impetus to improve calibration techniques that resulted in data that later met quality goals.
Table of Contents
Sections include:
Abstract
Introduction
Objectives
Methods
Calculations
Results and Discussion
Conclusions
Citation
Thoma, D. P., Irwin, R. J., & Penoyer, P. E., 2011, Documenting measurement sensitivity and bias of field-measured parameters in water quality monitoring programs. Environmental monitoring and assessment. Springer Science+Business Media. doi:10.1007/s10661-011-2347-5
Method Source
NPS
Source Organization Country
USA
Publication Year
2011
Special Notes
Authors are affilliated with a National Park Service (Government Agency-federal)
Item Type
Journal Article
Publication Source Type
Journal
Purpose
Data analysis
Monitoring program design
Design or Data Analysis Objectives
Compare locations
Compare treatments
Compliance with a threshold
Exploring/summarizing data
Complexity
Low
Media Emphasized
Surface Water
Media Subcategory
Special Topics
Characterizing the uncertainty of an estimated value
Measurements taken using a water quality sensor