ASTM: D1126:  Hardness in Water

  • Summary
  • Analytes
  • Revision
  • Data and Sites
Official Method Name
Standard Test Method for Hardness in Water
Current Revision
1996
Media
WATER
Instrumentation
Titration
Method Subcategory
Inorganic
Method Source
  ASTM
Citation
  Annual Book of ASTM Standards, Section 11, Water and Environmental Technology, Volume 11.01, Water (I)
Brief Method Summary
Calcium and magnesium ions in water are sequestered by the addition of disodium ethylenediamine tetraacetate. The end point of the reaction is detected by means of Chrome Black T , which has a red color in the presence of calcium and magnesium and a blue color when they are sequestered.
Scope and Application
This test method covers the determination of hardness in water by titration. This test method is applicable to waters that are clear in appearance and free of chemicals that will complex calcium or magnesium. It is possible to differentiate between hardness due to calcium ions and that due to magnesium ions by this test method.
Applicable Concentration Range
> 2 mg/L
Interferences
The substances shown in Table 1 represent the highest concentrations that have been found not to interfere with this determination. The test method is not suitable for highly colored waters, which obscure the color change of the indicator.
Quality Control Requirements
Not Included
Sample Handling
Collect the sample in accordance with Practice D 1066 or Practice D 3370 as applicable.
Maximum Holding Time
Relative Cost
Less than $50
Sample Preparation Methods